2,2-Bis[4-(p-aminophenoxy)phenyl]hexafluoropropane (HFBAPP)

GTC-394

Diamine Monomers

2,2-Bis[4-(p-aminophenoxy)phenyl]hexafluoropropane (HFBAPP)

CAS No.
69563-88-8
Catalogue ID
GTC-394

2,2-Bis[4-(p-aminophenoxy)phenyl]hexafluoropropane (HFBAPP), CAS 69563-88-8. Source-derived identification, physical data and applications are provided for catalogue reference; request the current specification, COA and SDS for the required grade.

Catalogue aliases / related identifiers

4-BDAF; 6FBAPP; BAPOFP; BIS-AF-A; 4,4′-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline; 4,4′-(Hexafluoroisopropylidene)bis[(4-aminophenoxy)benzene]; 4′,4′′′-(Hexafluoroisopropylidene)bis(4-phenoxyaniline); Benzenamine, 4,4'-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis-

Supplied catalogue source: GTC-394 · Page 65

Reference data — confirm before ordering or use

The information below is a structured migration from the supplied catalogue snapshot. It is not a current product specification, COA or SDS. Confirm the actual supplier, grade, batch documents, classification, packing and destination requirements for your enquiry.

HFBAPP CAS 69563-88-8 for Fluorinated Polyimide Synthesis

2,2-Bis[4-(p-aminophenoxy)phenyl]hexafluoropropane, commonly known as HFBAPP, is a fluorinated ether-containing aromatic diamine monomer used as a structural building block in high-performance polyimide and specialty polymer synthesis. Its hexafluoropropane core, aromatic backbone and flexible ether linkages make HFBAPP relevant to polymer systems where dielectric behavior, thermal resistance, solubility, processability and film-forming behavior need to be balanced.


Basic Information of HFBAPP

Product Name2,2-Bis[4-(p-aminophenoxy)phenyl]hexafluoropropane
AbbreviationHFBAPP
CAS Number69563-88-8
Product TypeFluorinated ether-containing aromatic diamine monomer
Molecular FormulaC27H20F6N2O2
Molecular Weight518.45 g/mol
AppearanceOff-white powder
Purity≥ 99%; batch data should be confirmed when COA is available
Main ApplicationFluorinated, low-dielectric and processable polyimide synthesis
Package1 kg/bottle, 20 kg/drum, or customized packaging
DocumentsSDS, TDS and available product information upon request; COA to be confirmed by batch availability
StorageKeep sealed, dry, and away from moisture
Molecular StructureHFBAPP CAS 69563-88-8 molecular structure

Key Features in Polyimide Design

  • Fluorinated ether-containing diamine structure, relevant to fluorinated polyimide diamine applications.

  • Hexafluoropropane structure may help reduce polarizability and support low-dielectric behavior depending on the paired dianhydride and polymer architecture.

  • Flexible ether linkages may improve solubility, chain mobility and processability in selected polyimide systems.

  • HFBAPP can be considered in flexible and processable polyimide systems where solubility, film formation and processing behavior are important.

  • Final material properties depend on monomer purity, dianhydride selection, solvent system, imidization conditions and polymer processing method.


Pairing HFBAPP with Dianhydride Monomers

In polyimide synthesis, HFBAPP may be evaluated with selected polyimide dianhydride monomers to design fluorinated, processable, low-dielectric and specialty PI systems. Fluorinated dianhydrides such as 6FDA CAS 1107-00-2 may be considered when optical, dielectric or moisture-related properties are part of the target polymer design.

Ether-containing dianhydrides such as ODPA CAS 1823-59-2 may further support processability and film-forming behavior, while rigid aromatic dianhydrides such as BPDA CAS 2420-87-3 or BTDA CAS 2421-28-5 may be considered when thermal resistance and dimensional stability are important.


Application Context of HFBAPP in Polyimide Systems

HFBAPP is typically used as a structural diamine monomer rather than a finished application material. It is commonly discussed in fluorinated, processable, low-dielectric and specialty polyimide material development, where hexafluoropropane structure and ether linkages can influence dielectric behavior, solubility, hydrophobicity and processing performance.


Related Polyimide Monomer Supply Guides

For a broader technical overview of both diamine and dianhydride monomer families, please review Polyimide Monomers: Diamines and Dianhydrides.


Related Polyimide Monomers

  • 6FAPB CAS 94525-05-0 – fluorinated ether diamine for transparent, flexible and low-dielectric PI material design.

  • 6FODA CAS 344-48-9 – fluorinated ether diamine for processable and low-dielectric polyimide systems.

  • 6FDA CAS 1107-00-2 – fluorinated dianhydride often considered in transparent and low-dielectric PI systems.


SDS, TDS and Technical Documentation

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